He said he stopped by some of her practice sessions to watch.
"At the end of the week, she asked me if I was available to coach her. I have the highest respect for her, but it was out of the question at the time. A few weeks later, I had a conversation with Serena, and the door opened for me, at least short term, to work with someone else," Mouratoglou said. "I will keep you updated on what's coming next soon."
Mouratoglou and Williams began working together shortly after she lost to Virginie Razzano in the first round of the 2012 French Open. That was the only opening-match exit for the American at any Grand Slam tournament until her injury-forced retirement in the first set on Centre Court against Aliaksandra Sasnovich on June 29.
Williams was 30 when Mouratoglou came aboard; she won 13 of her Grand Slam singles trophies before that and 10 since.
She will turn 41 in September and is currently ranked 246th because of her lack of action on tour.